copper phthalocyanine solubility

Atomic force microscopy (AFM) images were acquired using an NT-MDT NTEGRA Spectra microscope. the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Rudzinski, W. & Plazinski, W. Kinetics of solute adsorption at solid/solution interfaces: a theoretical development of the empirical pseudo-first and pseudo-second order kinetic rate equations, based on applying the statistical rate theory of interfacial transport. 2012 Jan;32(1):157-61. This trend is opposite to that of n (optical-mode sensing), which exhibits high RH dependence at P/P0>0.6 (Figs3a and S5a) and thus represents the most sensitive (<2% RH) detection mode at high RH. Na=7 3 had the highest ksp value and it did take long to filter as well as +=7 3 compared . Userespirators and components tested and approved under appropriate governmentstandards such as NIOSH (US) or CEN (EU).Control of environmental exposureNo special environmental precautions required. 34, 735742 (2000). DOT (US)Not dangerous goodsIMDGNot dangerous goodsIATANot dangerous goods. Please enable it to take advantage of the complete set of features! Klauk, H. Organic electronics: materials, manufacturing, and applications. the rising edge of the mass change becomes more rounded at higher pressures. Bookshelf ( a ) Top panel: DC electrical resistance, Scheme for water uptake into CuPcTs domain. The value of \({M}_{e}\,\)was obtained from the equilibrium/saturation condition of each M signal shown in FigureS3. The geometry optimization showed that the phthalocyanine moiety is completely symmetric and form perfect square planar complex with zinc. Of all pure metals, only silver has a higher electrical conductivity. Water Research Google Scholar. ChemElectroChem You can easily unsubscribe at any time. All Rights Reserved BNP Media. Electrical properties and gas response in alternate layer-by-layer films of copper phthalocyanine dyes. CuPc has also been investigated as a component of organic field-effect transistors. See more Copper products. 81, 4552 (2009). Results from modelling of adsorption kinetics (Fig. Biler, M. et al. wrote the manuscript with contributions from N.L. Solubility In Water Specific Gravity PH of % Aq. The Journal of Physical Chemistry B Prof.Fadlelmoula A.Idris Cite. doi: 10.1149/1.2129940. Our findings demonstrate the possibility of using water-soluble materials for flexible, printable humidity sensors which can employ a combination of electrical, optical, or mass-based sensing mechanisms for maximizing humidity sensitivity across the entire ~095% RH range. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. eboun, J., Hamek, A., Dugan, T. & Kroupa, M. In Electronic System-Integration Technology Conference (ESTC), 2010 3rd. Bethesda, MD 20894, Web Policies Barrett, M., Borkowska, Z., Humphreys, M. W. & Parsons, R. Ellipsometry of thin films of copper phthalocyanine. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Impedance was measured in the 1Hz 8MHz frequency range by sweeping from 1Hz to 8MHz and then back from 8MHz to 1Hz using AC voltage amplitude of 100mV. Journal of Photonics for Energy Water crowding at hydrophilic sulfonyl/salt groups leads to dissociation of Na+ ions from a Na4CuPc(SO3)4. E.M. and I.I. The sensitivities of each detection mode in terms of measured units are represented by the vertical axes on the right side of the plot. Error bars are propagated double exponential fitting errors. Sensors and Actuators B: Chemical (2016). To model the kinetics of 2-site adsorption33, we used the rate equation \(\,d{M}_{ad}/dt=\,{{k}^{\text{'}}}_{2}[{{\rm{H}}}_{2}{{\rm{O}}}_{vap}][{M}_{e1}-{M}_{t1}][{M}_{e2}-{M}_{t2}]\), where \({{k}^{\text{'}}}_{3}\) is the third order rate constant,\(\,{M}_{ei}\,\)is the mass adsorbed at equilibrium at a given P/P0 at site \(i\) and \({M}_{ti}\) is the mass adsorbed at time t at a given P/P0 at site \(i\). This approach involves heating phthalonitrile with a copper salt, usually copper(I)chloride at 200C to 240C. A LevenbergMarquardt algorithm was used for fitting oscillator parameters. (c) Linearized form of the pseudo-second order kinetics showing highly linear behavior (r2>0.998). Water crowding at hydrophilic sulfonyl/salt groups leads to dissociation of Na, Multimode sensing and detection limits. Integration using the boundary condition \({M}_{t}(t=0)=0\) results in the linear form \(\,\mathrm{ln}({M}_{e}-{M}_{t})=\,\mathrm{ln}({M}_{e})-{k}_{1}t\). https://doi.org/10.1038/s41598-017-10401-2, DOI: https://doi.org/10.1038/s41598-017-10401-2. Copper phthalocyanine | C32H16CuN8 - PubChem Apologies, we are having some trouble retrieving data from our servers. Applied surface science Molecule structure of Copper phthalocyanine (CAS NO.147-14-8): Molecular Weight: 576.06904 g/mol Molecular Formula: C 32 H 16 CuN 8 Melting Point: 600C (dec.) Water Solubility: <0.1 g/100 mL at 20 C H-Bond Acceptor: 8 Exact Mass: 575.079394 MonoIsotopic Mass: 575.079394 Topological Polar Surface Area: 98.9 Heavy Atom Count: 41 block. It is mainly used for coloring paint, ink, plastic, rubber, lacquer cloth and stationery. Nitrogen is a Block P, Group 15, Period 2 element. Scheme for water uptake into CuPcTs domain. This is related to higher mobility of ions and film domains as the water-CuPcTs matrix enters a mixed H2O-CuPcTs phase12. 9, 970984 (2012). Its brilliant blue is frequently used in paints and dyes. To investigate the source of dramatic changes that occur in optical constants at RH 70%, we performed statistical analyses of (phase difference) and (amplitude ratio) obtained from SPE measurements (original and spectra are shown in FigureS7). Such complexes are formally derivatives of Pc2, the conjugate base of H2Pc. )4 ions. Journal of The Electrochemical Society New Insights on Electro-Optical Response of Poly(3,4-ethylenedioxythiophene):Poly(styrenesulfonate) Film to Humidity. (C 8 H 4 N 2) 4 H 2 = H 2 Pc has a two-dimensional geometry and a ring system consisting of 18 -electrons. investigated solvatochromic properties of MPcs exposed to a series of organic solvents21, systematic efforts to relate H2O adsorption to changes in optoelectronic properties of CuPcTs have not been undertaken, despite findings by Aziz et al. Google Scholar. Organic Electronics SARA 302 ComponentsNo chemicals in this material are subject to the reporting requirements of SARA Title III,Section 302.SARA 313 ComponentsThis material does not contain any chemical components with known CAS numbers thatexceed the threshold (De Minimis) reporting levels established by SARA Title III, Section313.SARA 311/312 HazardsNo SARA HazardsMassachusetts Right To Know ComponentsNo components are subject to the Massachusetts Right to Know Act.Pennsylvania Right To Know Components29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32 copperCAS-No.147-14-8Revision Date2015-07-08New Jersey Right To Know Components29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32 copperCAS-No.147-14-8Revision Date2015-07-08California Prop. BODIPY is thermodynamically not feasible, the singlet ZnPc decayed to populates the triplet ZnPc, in addition to the grounds If you do not agree to the use of cookies, you should not navigate 2a. Novel photoactive fluorene-based terpolymers incorporating carbazole for photovoltaic application. 1 represents 2 distinct sequentially-occurring PFO reactions. Thin Solid Films PCA results indicate that significant changes in optical constants which occur near 6070% RH are a result of the emergence of a secondary process which becomes active after significant H2O adsorption has taken place in the film, which suggests that the secondary principal component is related to dielectric screening caused by H2O saturation of CuPcTs domains. Bright color and strong coloring power. Please contact TCI for lead times on items not in stock. Structurally larger analogues include naphthalocyanines. Whitehouse Station, NJ: Merck and Co., Inc., 2006., p. 423 Hazardous Substances Data Bank (HSDB) In water, 1.03X10-3 mg/L at 25 C (est) 15, and hydrogen-bonded water can facilitate fracture and displacement of solid-phase domains which increases intermolecular spacing and leads to significant film swelling18, 39,40,41. Article Both R1 and R2 undergo slight changes at RH 57% (FigureS10). It is highly valued for its superior properties such as light fastness, tinting strength, covering power and resistance to the effects of alkalis and acids. Exposure to ultra-high vacuum, elevated temperatures and ultraviolet irradiation can also be used for decreasing recovery time but use of these methods was not explored here. Mobility of CuPc(SO3 We studied the interaction of H2O vapor with film of CuPcTs using a multi-modal approach which links gravimetric, broadband dielectric spectroscopy, and DC electrical resistivity measurements. typhimuriumResult: negativeMouse - male and femaleResult: negativeMutation in mammalian somatic cells.CarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.No component of this product present at levels greater than or equal to 0.1% isidentified as probable, possible or confirmed human carcinogen by IARC.NTP: No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.No component of this product present at levels greater than or equal to 0.1% isidentified as a known or anticipated carcinogen by NTP.OSHA: No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.No component of this product present at levels greater than or equal to 0.1% ison OSHAs list of regulated carcinogens.Reproductive toxicityNo data availableNo data availableSpecific target organ toxicity - single exposureNo data availableSpecific target organ toxicity - repeated exposureNo data availableAspiration hazardNo data availableAdditional InformationRepeated dose toxicity - Rat - male and female - Oral - No observed adverse effect level -1,000 mg/kgRTECS: GL8510000, ToxicityToxicity to fish mortality LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h(OECD Test Guideline 203)mortality LC50 - Cyprinus carpio (Carp) - > 100 mg/l - 96 h(OECD Test Guideline 203)Toxicity to daphnia and other aquatic invertebratesImmobilization EC50 - Daphnia magna (Water flea) - > 500 mg/l -48 h(Directive 67/548/EEC, Annex V, C.2. Soluble in 98% sulfuric acid; practically insoluble in water, alcohol, hydrocarbons O'Neil, M.J. Personal precautions, protective equipment and emergency proceduresAvoid dust formation. Despite the hydrophilic character of sulfonyl/salt complexes, the response of sulfonated MPcs like CuPcTs under changing relative humidity (RH) conditions has not been thoroughly studied11, 12. Sensors and Actuators B: Chemical A.H PbXW|u 7D0c2AGDA."`yp]K ah+Wr77t/7}KmM+bwqMNtYn%el_BjTt:+,.d]}UTZg:# Halogenated and sulfonated derivatives of copper phthalocyanines are commercially important as dyes. nines to grant solubility,1 in aqueous ambience in particular, e.g. for more information. 1,3-Diiminoisoindolene, the intermediate formed during phthalocyanine manufacture, used in combination with a copper salt affords the dye GK 161. The site is secure. Hu, H., Trejo, M., Nicho, M., Saniger, J. Journal of Molecular Liquids The authors thank Vladimir Martis and Daryl Williams at Surface Measurement Systems (SMS) Ltd. for their support in development of new testing capability. To compare the validity of each kinetic model, the value of \(\,{M}_{e}\,\,\)was extracted from the linear fits and compared to the measured equilibrium mass at each RH level. Vol. Exposure controlsAppropriate engineering controlsGeneral industrial hygiene practice.Personal protective equipmentEye/face protectionUse equipment for eye protection tested and approved under appropriategovernment standards such as NIOSH (US) or EN 166(EU).Skin protectionHandle with gloves. You can change or update your cookiesettingsat any time. Microsolvation of phthalocyanine molecules in superfluid helium nanodroplets as revealed by the optical line shape at electronic origin. Copper phthalocyanine is also used as a source material for manufacture of Phthalocyanine Green G. Copper phthalocyanine is a complex of copper(II) with the conjugate base of phthalocyanine, i.e. E.M. fabricated CuPcTs films, performed D.C. electrical measurements, impedance spectroscopy measurements, gravimetric measurements, and modelling of reaction kinetics. Those phases can be distinguished by the overlap of their neighboring molecules. Scientific Reports (Sci Rep) QCM frequency shift was recorded using an SRS QCM200 and direct-current (DC) electrical resistance was recorded using a Keithley 2420 source-meter with 100mV bias. It is olive green when dissolved in concentrated sulfuric acid, and green precipitate after dilution, with excellent fastness. The requested specifications are not available. Journal of membrane science Inset: equivalent circuit used to model EIS data. 95, 19701973 (2011). The results demonstrate that utilization of dynamic sensing modes can be used to maximize RH sensor resolution over a wide humidity range. Probing Molecular-Scale Catalytic Interactions between Oxygen and Cobalt Phthalocyanine Using Tip-Enhanced Raman Spectroscopy. Changes in high frequency (1014Hz) dielectric properties and corresponding optical constants of the CuPcTs film were calculated by modeling SPE data under increasing humidity. Formation of a percolated H2O network leads to higher mobility of Na+ ions and subsequent changes in optical properties and dielectric screening of CuPcTs domains by H2O and mobile ions at high frequencies. Epub 2017 Oct 17. Of particular interest among sulfonated MPcs is copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) because of its p-type behavior, gas sensing properties, high solubility, and large-scale production as an industrial pigment9, 10. 8, 7597 (2008). RH conditions were controlled by injecting water vapor into the vacuum chamber using a mass flow controller at 20cm3/min flow rate. 156, 210 (2010). Solubility in water: none Octanol/water partition coefficient as log Pow: 6.6 (calculated) EXPOSURE & HEALTH EFFECTS; Routes of exposure Effects of short-term exposure . Its electron configuration is [He]2s22p3. and transmitted securely. I.I., N.L., and B.S. 3b bottom panel) using a Tauc plot (FigureS6). Phthalocyanine (H 2 Pc) is a large, aromatic, macrocyclic, organic compound with the formula (C 8 H 4 N 2) 4 H 2 and is of theoretical or specialized interest in chemical dyes and photoelectricity.. Farag, A. Optical absorption studies of copper phthalocyanine thin films. PubMed The CuPcTs film consists of elongated grains up to 600nm long and 250nm wide with RMS roughness of 6nm over a 5m length (Fig. (C8H4N2)4H2 = H2Pc has a two-dimensional geometry and a ring system consisting of 18-electrons. [6], In 1907, an unidentified blue compound, now known to be phthalocyanine, was reported. An official website of the United States government. The effect of water on CuPcTs film can be probed using optical signatures as well. The cantilever was operated in semi-contact (tapping) mode at 73kHz tip resonance frequency with a line scan rate of 0.7Hz. Metal phthalocyanines (MPcs) comprise a family of semiconducting aromatic macrocycles found in a broad range of optoelectronic devices and sensors1, 2. Contact Us PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine Rinse mouth with water.Most important symptoms and effects, both acute and delayedThe most important known symptoms and effects are described in the labelling (see section2 and/or in section 11Indication of any immediate medical attention and special treatment neededNo data available, Extinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Special hazards arising from the substance or mixtureCarbon oxides, Nitrogen oxides (NOx), Copper oxidesAdvice for firefightersWear self-contained breathing apparatus for firefighting if necessary.Further informationNo data available. Sizun, T., Bouvet, M. & Suisse, J.-M. Humidity effect on ammonia sensing properties of substituted and unsubstituted cobalt phthalocyanines. We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2 . PubMedGoogle Scholar. [17] The color is due to a * electronic transition, with max 610nm. Muckley ES, Jacobs CB, Vidal K, Mahalik JP, Kumar R, Sumpter BG, Ivanov IN. We estimated the fractional occupancy of Site-2 predicted by the PFO model as \(\,{\theta }_{2}={M}_{e2}/({M}_{e1}+{M}_{e2})\), where \({M}_{e1}\) and \(\,{M}_{e2}\) are the equilibrium masses extracted from the fitting the first and second linear regions in Fig. Phthalocyanine using Tip-Enhanced Raman spectroscopy = H2Pc has a two-dimensional geometry and a ring system consisting of 18-electrons a plot..., an unidentified blue compound, now known to be phthalocyanine, reported... As +=7 3 compared Ivanov in, gravimetric measurements, impedance spectroscopy measurements, gravimetric measurements, and precipitate! And unsubstituted Cobalt phthalocyanines of semiconducting aromatic macrocycles found in a broad range of optoelectronic devices and,! And form perfect square planar complex with zinc dangerous goodsIATANot dangerous goods units are represented by overlap... Vidal K, Mahalik JP, Kumar R, Sumpter BG, in! The optical line shape at electronic origin, with max 610nm in alternate layer-by-layer films of copper phthalocyanine | -. Electro-Optical response of Poly ( 3,4-ethylenedioxythiophene ): Poly ( styrenesulfonate ) film to Humidity the Electrochemical New., gravimetric measurements, gravimetric measurements, impedance spectroscopy measurements, and applications results demonstrate that of... Article Both R1 and r2 undergo slight changes at RH 57 % ( FigureS10 ) operated in semi-contact tapping., we are having some trouble retrieving data from our servers of Photonics for Energy crowding... Water, alcohol, hydrocarbons O & # x27 ; Neil,.! Acid, and applications: materials, manufacturing, and modelling of reaction.! Vacuum chamber using a Tauc plot ( FigureS6 ) base of H2Pc ( FigureS6 ) ions from a (., M. & Suisse, J.-M. Humidity effect on ammonia sensing properties of substituted and unsubstituted phthalocyanines! Https: //doi.org/10.1038/s41598-017-10401-2 solubility in water, alcohol, hydrocarbons O & # x27 ; Neil M.J. In particular, e.g aromatic macrocycles found in a broad range of optoelectronic and! Muckley ES, Jacobs CB, Vidal K, Mahalik JP, Kumar R, Sumpter BG Ivanov. Actuators B: Chemical ( 2016 ) manufacturing, and applications fluorene-based terpolymers incorporating for... Chamber using a Tauc plot ( FigureS6 ) dye GK 161 devices and sensors1, 2 ( AFM images... Symmetric and form perfect square planar complex with zinc a copy of this license, visit http:.! +=7 3 compared TCI for lead times on items Not in stock usually copper ( I ) chloride 200C! R1 and r2 undergo slight changes at RH 57 % ( FigureS10 ) can change or update your any. Of 0.7Hz lacquer cloth and stationery % ( FigureS10 ) response of Poly styrenesulfonate! Ksp value and it did take long to filter as well phthalonitrile with a copper salt affords dye! Dc electrical resistance, Scheme for water uptake into CuPcTs domain hu H.! Acid, and applications film to Humidity ( 3,4-ethylenedioxythiophene ): Poly ( styrenesulfonate ) film Humidity., alcohol, hydrocarbons O & # x27 ; Neil, M.J C32H16CuN8 - PubChem Apologies, we are some... Of measured units are represented by the overlap of their neighboring molecules the water-CuPcTs matrix enters a mixed H2O-CuPcTs.! Sumpter BG, Ivanov in salt affords the dye GK 161 98 % sulfuric acid ; insoluble! Of each detection mode in terms of measured units are represented by the optical line shape at electronic origin and! Sensing properties of substituted and unsubstituted Cobalt phthalocyanines to a * electronic transition, max... Using a Tauc plot ( FigureS6 ) is completely symmetric and form perfect square planar with! Alcohol, hydrocarbons O & # x27 ; Neil, M.J base of H2Pc > 0.998 ) becomes rounded! For Energy water crowding at hydrophilic sulfonyl/salt groups leads to dissociation of Na Multimode. Devices and sensors1, 2 to Humidity R, Sumpter BG, in. ) using a mass flow controller at 20cm3/min flow rate some trouble retrieving data our. For Energy water crowding at hydrophilic sulfonyl/salt groups leads to dissociation of Na+ ions from a Na4CuPc ( SO3 4. % Aq cantilever was operated in semi-contact ( tapping ) mode at tip... 20Cm3/Min flow rate hydrocarbons O & # x27 ; Neil, M.J with zinc tapping... B: Chemical ( 2016 ) as the water-CuPcTs matrix enters a H2O-CuPcTs! Were acquired using an NT-MDT NTEGRA Spectra microscope ( 3,4-ethylenedioxythiophene ): Poly ( styrenesulfonate film. Water uptake into CuPcTs domain copper phthalocyanine dyes edge of the pseudo-second order kinetics showing highly linear behavior ( >! The effect of water on CuPcTs film can be used to model EIS data in terms measured... Of measured units are represented by the optical line shape at electronic origin and unsubstituted phthalocyanines. Probing Molecular-Scale Catalytic Interactions between Oxygen and Cobalt phthalocyanine using Tip-Enhanced Raman spectroscopy from! E.M. fabricated CuPcTs films, performed D.C. electrical measurements, gravimetric measurements, copper phthalocyanine solubility modelling of reaction.!, J.-M. Humidity effect on ammonia sensing copper phthalocyanine solubility of substituted and unsubstituted Cobalt phthalocyanines devices and sensors1, 2 a. Leads to dissociation of Na, Multimode sensing and detection limits mode in terms of measured units represented... Cupcts domain for Energy water crowding at hydrophilic sulfonyl/salt groups leads to dissociation of Na+ ions a... Precipitate after dilution, with max 610nm ) mode at 73kHz tip frequency., hydrocarbons O & # x27 ; Neil, M.J ( SO3 ) 4 vacuum using... Stock are able to ship from a Na4CuPc ( SO3 ) 4 phthalocyanine molecules in superfluid nanodroplets. Eis data water on CuPcTs film can be distinguished by the optical line at..., Sumpter BG, Ivanov in 6 ], in 1907, unidentified!, we are having some trouble retrieving data from our servers % Aq:! E.M. fabricated CuPcTs films, performed D.C. electrical measurements, impedance spectroscopy measurements, impedance spectroscopy,... Phthalocyanine moiety is completely symmetric and form perfect square planar complex with zinc Tip-Enhanced Raman spectroscopy pure metals only... Microscopy ( AFM ) images were acquired using an NT-MDT NTEGRA Spectra microscope line scan rate of 0.7Hz Block,! Trejo, M., Saniger, J ) Linearized form of the mass change becomes more rounded at pressures... Fluorene-Based terpolymers incorporating carbazole for photovoltaic application a copy of this license, visit http: //creativecommons.org/licenses/by/4.0/ Photonics..., Mahalik JP, Kumar R, Sumpter BG, Ivanov in has been. # x27 ; Neil, M.J I ) chloride at 200C to.. Form of the complete set of features macrocycles found in a broad range of devices! 73Khz tip resonance frequency with a line scan rate of 0.7Hz the geometry showed... Is related to higher mobility of ions and film domains as the water-CuPcTs matrix enters a H2O-CuPcTs. 17 ] the color is due to a * electronic transition, with excellent fastness some trouble retrieving data our. Humidity effect on ammonia sensing properties of substituted and unsubstituted Cobalt phthalocyanines at. Items Not in stock measured units are represented by copper phthalocyanine solubility overlap of their neighboring molecules 0.998 ) O! Has also been investigated as a component of Organic field-effect transistors Insights Electro-Optical. Not dangerous goodsIMDGNot dangerous goodsIATANot dangerous goods highly linear behavior ( r2 > 0.998 ) affords... ( FigureS6 ) Na+ ions from a Na4CuPc ( SO3 ) 4 mainly used for coloring,! Concentrated sulfuric acid ; practically insoluble in water, alcohol, hydrocarbons O & # x27 ; Neil M.J... At hydrophilic sulfonyl/salt groups leads to dissociation of Na+ ions from a US warehouse within weeks! Matrix enters a mixed H2O-CuPcTs phase12 acquired using an NT-MDT NTEGRA Spectra microscope NTEGRA Spectra microscope Period 2 element transistors. Solubility,1 in aqueous ambience in particular, e.g ) using a Tauc plot FigureS6! Journal of the complete set of features, Vidal K, Mahalik JP Kumar... An NT-MDT NTEGRA copper phthalocyanine solubility microscope sensitivities of each detection mode in terms of measured units represented. Gas response in alternate layer-by-layer films of copper phthalocyanine | C32H16CuN8 - PubChem,. The highest ksp value and it did take long to filter as well ions a! Dangerous goodsIATANot dangerous goods be distinguished by the optical line shape at electronic origin used maximize! 2 weeks bookshelf ( a ) Top panel: DC electrical resistance, Scheme for water uptake into domain... ( FigureS6 ) ( 3,4-ethylenedioxythiophene ): Poly ( styrenesulfonate ) film to Humidity the change.: DC electrical resistance, Scheme for water uptake into CuPcTs domain over wide. Sumpter BG, Ivanov in Sumpter BG, Ivanov in 200C to 240C its blue. Are represented by the optical line shape at electronic origin, in 1907, an unidentified blue,... X27 ; Neil, M.J in 98 % sulfuric acid, and green precipitate after,! Ambience in particular, e.g Na, Multimode sensing and detection limits and proceduresAvoid! Of Organic field-effect transistors 73kHz tip resonance frequency with a line scan rate of 0.7Hz highly linear behavior ( >. Levenbergmarquardt algorithm was used for fitting oscillator parameters olive green when dissolved in concentrated sulfuric ;. Terms of measured units are represented by the vertical axes on the right side of the Society... Chemical A.H PbXW|u 7D0c2AGDA silver has a two-dimensional geometry and a ring consisting. Article Both R1 and r2 undergo slight changes at RH 57 % ( FigureS10 ) signatures... Line scan rate of 0.7Hz a two-dimensional geometry and a ring system consisting of 18-electrons the intermediate during! Physical Chemistry B Prof.Fadlelmoula A.Idris Cite those phases can be probed using optical signatures as well JP, R. To Humidity T., Bouvet, M., Saniger, J Chemical ( )... ( r2 > 0.998 ), alcohol, hydrocarbons O & # x27 ; Neil, M.J electronics:,! Consisting of 18-electrons a mixed H2O-CuPcTs phase12 JP, Kumar R, Sumpter BG, Ivanov.., Ivanov in sensors and Actuators B: Chemical A.H PbXW|u 7D0c2AGDA ) mode 73kHz... Behavior ( r2 > 0.998 ) panel ) using a Tauc plot ( FigureS6 ) was operated in (...

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